Electrode heat balances of electrochemical cells: application to NaCl electrolysis

Autor:	Ryuichi Takeda, Yasuhiko Ito, Y. Ogata, Shiro Yoshizawa
Rok vydání:	1985
Předmět:	Electrolysis General Chemical Engineering Sodium Inorganic chemistry chemistry.chemical_element Electrochemistry Electrochemical cell law.invention chemistry law Seebeck coefficient Thermoelectric effect Electrode Materials Chemistry Chlorine
Zdroj:	Journal of Applied Electrochemistry. 15:209-215
ISSN:	1572-8838 0021-891X
DOI:	10.1007/bf00620935
Popis:	This paper deals with a method of estimating single electrode heat balances during the electrolysis of molten NaCl-ZnCl2 in a cell using aβ-alumina diaphragm. By measuring the thermoelectric power of the thermogalvanic cells: (T) Na/β-alumina/NaCl-ZnCl2/β-alumina/Na(T+dT) and (T) C,Cl2/NaCl-ZnCl2/Cl2,C(T+dT) the single electrode Peltier heat for sodium deposition and for chlorine evolution at 370° C were estimated to be −0.026±0.001 JC−1 and+0.614±0.096 J C−1, respectively.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::e7afb4314331fcd7aa0052f5cd6225e1 https://doi.org/10.1007/bf00620935 Zobrazit plný text záznamu Full text from SpringerLink