The influence of singlet-triplet transitions on non-stationary kinetics of radical recombination in homogeneous solutions. I. General theory and analytical model treatment

Autor:	K.M. Salikhov, E.B. Krissinel, N.V. Shokhirev
Rok vydání:	1989
Předmět:	Reaction rate constant General theory Homogeneous Chemistry Kinetics General Physics and Astronomy Physical chemistry Singlet state Physical and Theoretical Chemistry Molecular physics Recombination Magnetic field
Zdroj:	Chemical Physics. 137:197-205
ISSN:	0301-0104
DOI:	10.1016/0301-0104(89)87105-8
Popis:	An expression is derived for the non-stationary rate constant of bimolecular reactions in the quasiresonant approximation for particles with internal structure. The influence of S-T0 singlet-triplet transitions on the kinetics of neutral radical recombination in a magnetic field is examined. Asymptotic expressions for the rate constant of non-stationary recombination are obtained for both short and long times. It was found that an oscillatory regime exists in homogeneous reactions.
Databáze:	OpenAIRE
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