Syntheses of 3,5-Dimethylspiro[5.5]undeca-2,4-diene-1,8-dione and 7,11-Dimethylspiro[5.5]undeca-7,10-diene-2,9-dione

Autor: Kalyan Kumar Bhattagharya, Parimal Krishna Sen
Rok vydání: 1979
Předmět:
Zdroj: Bulletin of the Chemical Society of Japan. 52:2173-2174
ISSN: 1348-0634
0009-2673
DOI: 10.1246/bcsj.52.2173
Popis: Syntheses of 1-diazo-5-(2-hydroxy-4,6-dimethylphenyl)-2-pentanone and 1-diazo-5-(4-hydroxy-2,6-dimethylphenyl)-2-pentanone and their acid catalysed spiroannulation to 3,5-dimethylspiro[5.5]undeca-2,4-diene-1,8-dione and 7,11-dimethylspiro[5.5]undeca-7,10-diene-2,9-dione respectively via Ar1-6 participation are described. Succinylation of 3,5-dimethylanisole is also discussed.
Databáze: OpenAIRE