ChemInform Abstract: Cooperative Multimetallic Catalysis Using Metallosalens

Autor:	Arjan W. Kleij, Sander J. Wezenberg, Robert M. Haak
Rok vydání:	2010
Předmět:	Reaction rate Chemistry Feature (computer vision) Design elements and principles General Medicine Combinatorial chemistry Bimetallic strip Catalysis
Zdroj:	ChemInform. 41
ISSN:	1522-2667 0931-7597
DOI:	10.1002/chin.201033231
Popis:	Metallosalen complexes are able to catalyze several transformations via a bimetallic, cooperative pathway. Various strategies to induce simultaneous activation by two metal centers with multinuclear catalysts have been reported to date, leading to higher reaction rates and selectivities in existing reactions. In some cases, new reactions could be realized that were previously not possible. The design principles, the most successful approaches and the catalytic applications of multinuclear metallosalen catalysts are discussed in this feature article.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::e76bf1e474488bae51419bd06682d367 https://doi.org/10.1002/chin.201033231 Zobrazit plný text záznamu Plný text