Synergism in combustion processes
| Autor: | G. V. Balayan, N. V. Chapysheva, V. V. Azatyan, V. M. Prokopenko, S. K. Abramov |
|---|---|
| Rok vydání: | 2016 |
| Předmět: |
010405 organic chemistry
Chemistry Inorganic chemistry chemistry.chemical_element Thermodynamics General Chemistry 010402 general chemistry Combustion Chain termination 01 natural sciences Nitrogen Catalysis 0104 chemical sciences Computer Science Applications law.invention Ignition system law Modeling and Simulation Flame propagation |
| Zdroj: | Kinetics and Catalysis. 57:573-577 |
| ISSN: | 1608-3210 0023-1584 |
| DOI: | 10.1134/s0023158416050037 |
| Popis: | The effect of CF3H, CF4, and N2 on the ignition of methane–air mixtures has been investigated. The effect of trifluoromethane is due to its being involved in reaction chain termination. A nonadditive effect of trifluoromethane and nitrogen on the concentration limits of ignition and flame propagation in methane–air mixtures has been predicted and revealed. The synergistic effect arises from the exponential dependence of the rate of the chain process on the concentrations of the initial components. |
| Databáze: | OpenAIRE |
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