The reactivity of cyclohexadienyl(cyclopentadienyl)iron derivatives

Autor:	A. N. Nesmeyanov, N. A. Vol'kenau, L. S. Shilovtseva, V. A. Petrakova
Rok vydání:	1975
Předmět:	Inorganic Chemistry chemistry.chemical_compound Cyclopentadienyl complex Ferrocene Chemistry Organic Chemistry Materials Chemistry Organic chemistry Bromosuccinimide Reactivity (chemistry) Physical and Theoretical Chemistry Biochemistry Medicinal chemistry
Zdroj:	Journal of Organometallic Chemistry. 85:365-373
ISSN:	0022-328X
DOI:	10.1016/s0022-328x(00)80310-1
Popis:	Oxidation of exo -substituted (cyclohexadienyl)cyclopentadienyliron derivatives, exo -RC 6 H 6 FeC 5 H 5 (R = C 2 H 5 , C 6 H 5 CH 2 or C 5 H 5 ), by (Ph 3 C)BF 4 or bromosuccinimide proceeds by either of two routes, exo -R abstraction or endo H abstraction. Mixtures of [C 6 H 6 FeC 5 H 5 ] + and [RC 6 H 5 FeC 5 H 5 ] + axe formed in the reactions. The tendency for R-abstraction rises along the series C 5 H 5 C 2 H 5 6 H 5 CH 2 . When heated, the compounds (arene H) FeC 5 H 5 axe transformed to ferrocene.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::e73deca827a79e35d223197f9eb5b815 https://doi.org/10.1016/s0022-328x(00)80310-1 Zobrazit plný text záznamu