Application of Organocerium Reagents for the Efficient Conversion of Z-α,β-Unsaturated Weinreb Amides to Z-α,β-Unsaturated Ketones

Autor: Atsushi Yamakawa, Tsugihiko Hidaka, Satoshi Kojima
Rok vydání: 2005
Předmět:
Zdroj: ChemInform. 36
ISSN: 1522-2667
0931-7597
DOI: 10.1002/chin.200536034
Popis: The reactions ofZ-rich unsaturated Weinreb amides with organolithium and organocerium reagents were examined. Taking in consideration both the extent of geometry retention and cleanness of the reaction, organocerium reagents were more effective for the conversion to Z-α,β-unsaturated ketones.
Databáze: OpenAIRE