Solvothermal synthesized LiMn1−xFexPO4@C nanopowders with excellent high rate and low temperature performances for lithium-ion batteries
| Autor: | Bang-Kun Zou, Yu-Ting Zhou, Ran Yu, Chun-Hua Chen, Miao-Miao Deng, Jia-Ying Liao |
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| Rok vydání: | 2016 |
| Předmět: |
High rate
Materials science General Chemical Engineering Analytical chemistry chemistry.chemical_element Nanotechnology 02 engineering and technology General Chemistry 010402 general chemistry 021001 nanoscience & nanotechnology Electrochemistry 01 natural sciences 0104 chemical sciences Ion chemistry Particle-size distribution Energy density Lithium 0210 nano-technology Layer (electronics) Carbon |
| Zdroj: | RSC Adv.. 6:52271-52278 |
| ISSN: | 2046-2069 |
| DOI: | 10.1039/c6ra12472k |
| Popis: | Mixed-carbon coated LiMn1−xFexPO4 (x = 0, 0.2, 0.5, 1) nano-particles are synthesized by a novel solvothermal approach. All of these powders possess a uniform particle size distribution around 150 nm and a carbon coating layer of about 2 nm. The LiMn1−xFexPO4@C samples with a carbon content of 2 wt% have an optimal electrochemical performance. The average voltage platform of LiMn1−xFexPO4@C increases with the increased Mn/Fe ratio, but declines gradually during electrochemical cycling. The LiMn0.5Fe0.5PO4 sample shows a high energy density (568 W h kg−1), good cycleability (97.1%, 100 cycles) and excellent rate capability (120.2 mA h g−1, 20C) at room temperature. Simultaneously, the LiMn0.5Fe0.5PO4 and LiFePO4 samples also show excellent low temperature electrochemical performance with specific capacities of 109.4 and 138.8 mA h g−1 with average discharge voltages of 3.476 V and 3.385 V, respectively, at −12 °C. Even at −20 °C, their discharge specific capacities are 71.7 and 82.3 mA h g−1 at 3C, respectively. |
| Databáze: | OpenAIRE |
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