Structure and inclusion property of supramolecular host framework [H2 L1][XCl4], L1 = N,N,N′,N′-tetra-p-methoxybenzyl-ethylenediamine; X = Fe, Co, Pd
| Autor: | Jian Tong, Fang Guo, Hong-lin Li, Na Lu, Lei Li, Hong-cui Yu |
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| Rok vydání: | 2012 |
| Předmět: |
Hydroquinone
biology Stereochemistry Supramolecular chemistry Ethylenediamine Protonation Condensed Matter Physics biology.organism_classification Medicinal chemistry Metal chemistry.chemical_compound chemistry visual_art Diamine visual_art.visual_art_medium Tetra Molecule Physical and Theoretical Chemistry |
| Zdroj: | Structural Chemistry. 24:1111-1119 |
| ISSN: | 1572-9001 1040-0400 |
| DOI: | 10.1007/s11224-012-0143-7 |
| Popis: | In this paper, we have used the hydrogen-bonding interactions, combining the designed diamine ligands and anionic metal chlorides, into the construction of a series of new pillar-layered supramolecular complexes. The flexible molecule N,N,N′,N′-tetra-p-methoxybenzyl-ethylenediamine (L1) bearing doubly protonated H-bond donors, has been synthesized and reacted with the metal chlorides (such as [PdCl4]2−, [FeCl4]− and [CoCl4]2−) via weak C–H···Cl interactions, yielding crystal products [H2 L1]2+·Cl−·[FeCl4]− (1), 0.5H2O ⊂ [H2 L1]2+·Cl−·0.5[PdCl4]2− (2) and [2-hydroxy naphthyl]1.5 ⊂ 2[H2 L1]2+·2Cl−·[CoCl4]2− (3). The 3-D networks are organic double layers formed by the self-assembly of the ligands through extensive hydrogen-bonding interactions (C–H···O or C–H···π interactions) and further interconnected by [PdCl4]2−/[FeCl4]−/[CoCl4]2− in a pillar fashion, constructing into pillar-layered networks with channels accessible to various guest molecules. The inclusion property of [H2 L1][CoCl4] was studied, varieties of guest molecules, such as 2-hydroxy naphthyl, phenanthrene and hydroquinone, can be included in the framework. |
| Databáze: | OpenAIRE |
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