Iron(III) phthalocyanine-chloride-catalyzed synthesis of sulfones from sulfonylhydrazones
| Autor: | Junlong Zhao, Shi-Huan Guo, Bang Chen, Chengwen Hua, Jun Qiu, Xiaofeng Gou |
|---|---|
| Rok vydání: | 2016 |
| Předmět: |
010405 organic chemistry
Organic Chemistry chemistry.chemical_element Substrate (chemistry) 010402 general chemistry 01 natural sciences Biochemistry Chloride Combinatorial chemistry Sulfur 0104 chemical sciences Catalysis chemistry.chemical_compound chemistry Intramolecular force Drug Discovery Phthalocyanine medicine Organic chemistry medicine.drug |
| Zdroj: | Tetrahedron Letters. 57:2375-2378 |
| ISSN: | 0040-4039 |
| Popis: | In this study, sulfones are synthesized from sulfonylhydrazones catalyzed by iron(III) phthalocyanine chloride. This reaction offers broad substrate scope, occurs under mild conditions, utilized readily available reactants, and forms products in good-to-high yields. Crossover experiments reveal that the reaction occurs via an intramolecular process, which is possibly different from other studies reported previously. The method provides a novel, simple, and promising strategy for synthesizing functionalized sulfones in the research field of sulfur chemistry. |
| Databáze: | OpenAIRE |
| Externí odkaz: |
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