ChemInform Abstract: CONVERSION OF 2-ALKYLCYCLOPENTANONES INTO 2-ALKYL-2-CYCLOPENTENONES WITH HYDRATED FERRIC CHLORIDE AND CUPRIC CHLORIDE

Autor:	G. Cardinale, J. P. Ward, J. A. M. Laan, S. W. Russell
Rok vydání:	1982
Předmět:	Solvent chemistry.chemical_classification chemistry Cupric chloride Polymer chemistry medicine Ferric General Medicine Chloride Alkyl medicine.drug
Zdroj:	Chemischer Informationsdienst. 13
ISSN:	0009-2975
DOI:	10.1002/chin.198239182
Popis:	Hydrated ferric chloride, FeCl3·6 H2O, in a polar, hydroxylic solvent converted 2-alkylcyclopentanones directly into 2-alkyl-2-cyclopentenones on heating in the presence of air. Yields of isolated products were about 40 %. The scope of the reaction is discussed. With cupric chloride, chloroketones were formed as intermediates, which could be dehydrochlorinated to 2-alkyl-2-cyclopentenones in similar yields.
Databáze:	OpenAIRE
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