Synthesis and Crystal Structure of a Novel Porphyrin-based Metal Carboxylate Framework with Large Void Volume
| Autor: | Satoshi Matsunaga, Nanako Endo, Wasuke Mori |
|---|---|
| Rok vydání: | 2017 |
| Předmět: |
010405 organic chemistry
Inorganic chemistry chemistry.chemical_element General Chemistry Zinc Crystal structure 010402 general chemistry Block (periodic table) 01 natural sciences Porphyrin 0104 chemical sciences Metal chemistry.chemical_compound Crystallography chemistry Volume (thermodynamics) visual_art Void volume visual_art.visual_art_medium Carboxylate |
| Zdroj: | Chemistry Letters. 46:937-939 |
| ISSN: | 1348-0715 0366-7022 |
| DOI: | 10.1246/cl.170297 |
| Popis: | We report the synthesis of a novel porphyrin-based metal carboxylate framework, [Cu2(ZnBBCPPP)(H2O)2]·6DMF·11H2O (BBCPPP-Cu2), with a large void volume, by using a two-dimensionally expanded building block: {bis[3,5-bis(4-carboxyphenyl)phenyl]porphyrinato}zinc (ZnBBCPPP). Single-crystal X-ray analysis of BBCPPP-Cu2 revealed a three-dimensional network. The void volume per unit cell of BBCPPP-Cu2 is 76.8%, which is considerably larger than that of previously reported porphyrin-based MOFs. |
| Databáze: | OpenAIRE |
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