ChemInform Abstract: N-Heterocyclic Carbene Complexes of Rhodium: Structure, Stability and Reactivity

Autor:	Cathleen M. Crudden, Jeremy M. Praetorius
Rok vydání:	2008
Předmět:	chemistry.chemical_compound chemistry Transition metal chemistry.chemical_element Reactivity (chemistry) General Medicine Carbene Combinatorial chemistry Organometallic chemistry Hydroformylation Rhodium
Zdroj:	ChemInform. 39
ISSN:	1522-2667 0931-7597
Popis:	The organometallic chemistry of N-heterocyclic carbene complexes of the transition metals has received significant attention over the past ten years, especially with respect to complexes of Pd and Ru. The present Perspective highlights the chemistry of NHC complexes of another important transition metal, Rh. The application of Rh–NHC complexes in the industrially significant reactions of hydrogenation and hydroformylation is described. In order to accurately assess the activity of these complexes, their stability must be carefully determined. Various synthetic routes to Rh–NHC complexes are also described.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::e689e2ba2ccbd53a5b7478eff39219f1 https://doi.org/10.1002/chin.200849231 Zobrazit plný text záznamu Plný text