Mass spectrometric study of N-oxides of quinolysidine alkaloids of the matrine series
Autor: | Z. S. Ziyavidinova, N. S. Vul'fson, Vladimir G. Zaikin |
---|---|
Rok vydání: | 1974 |
Předmět: | |
Zdroj: | Bulletin of the Academy of Sciences of the USSR Division of Chemical Science. 23:1657-1661 |
ISSN: | 1573-9171 0568-5230 |
DOI: | 10.1007/bf00923183 |
Popis: | 1. The mass spectra of N-oxides of matrine, allomatrine, sophoridine, isosophoridine, sophocarpine, and isosophoramine were studied. 2. The ions [M-17]+ are formed, at least partially, from molecular ions in one step by elimination of the OH radical. 3. With the aid of the peaks of the metastable ions and a comparison with the mass spectra of unoxidized alkaloids, the origin of individual ions in the spectra of the N-oxides studied was determined. |
Databáze: | OpenAIRE |
Externí odkaz: |