Ro-vibrational levels for HF2+: The effect of rotation on vibrational splittings for proton transfer

Autor:	Tucker Carrington, Xudong T. Wu, I. P. Hamilton
Rok vydání:	2000
Předmět:	Exact results Hydrogen compounds Proton Chemistry General Physics and Astronomy Rotational–vibrational spectroscopy Physical and Theoretical Chemistry Atomic physics Rotation Coriolis coupling Quantum tunnelling Ion
Zdroj:	The Journal of Chemical Physics. 113:7273-7275
ISSN:	1089-7690 0021-9606
DOI:	10.1063/1.1313540
Popis:	Ro-vibrational energy levels of HF2+ are computed to study the effect of rotation on tunneling splittings for proton transfer. The effect of rotation is small but systematic. Numerically exact results are tabulated and trends are discussed in terms of a model that neglects Coriolis coupling.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::e65778e8839b39d8de1ee594bb0dcb07 https://doi.org/10.1063/1.1313540 Zobrazit plný text záznamu