Incorporating Pd(OAc)2on Imine Functionalized Microporous Covalent Organic Frameworks: A Stable and Efficient Heterogeneous Catalyst for Suzuki-Miyaura Coupling in Aqueous Medium
| Autor: | Velu Sadhasivam, Rajendiran Balasaravanan, Ayyanar Siva, Chinnadurai Chithiraikumar |
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| Rok vydání: | 2017 |
| Předmět: |
Thermogravimetric analysis
Materials science 010405 organic chemistry Inorganic chemistry Imine General Chemistry Microporous material 010402 general chemistry Heterogeneous catalysis 01 natural sciences Coupling reaction 0104 chemical sciences Catalysis chemistry.chemical_compound chemistry Solid-state nuclear magnetic resonance Metal-organic framework |
| Zdroj: | ChemistrySelect. 2:1063-1070 |
| ISSN: | 2365-6549 |
| DOI: | 10.1002/slct.201601440 |
| Popis: | Imine-based microporous covalent organic frameworks, TATAE were synthesized from condensation of 4,4′,4“-(1,3,5-triazine-2,4,6-triyl)tribenzaldehyde and 1,4-diaminobenzene, followed by Pd(OAc)2 was incorporated on TATAE (Pd/TATAE). The as-synthesized Pd/TATAE was thoroughly characterized by Fourier Transform-Infrared Spectroscopy, 13C CP-MAS solid state nuclear magnetic resonance, powder X-ray diffraction, X-ray photoelectron spectroscopy, thermo gravimetric analysis, scanning electron microscopy and transmission electron microscopy. The Pd/TATAE was employed as a solid catalyst for Suzuki-Miyaura coupling reactions in an environmentally benign water medium at room temperature, which exhibited a good catalytic activity with excellent yield. In addition, the heterogeneous nature of the catalyst was checked by Shelton test, this catalyst can be recycled more than four times with only a minor loss of its catalytic activity. |
| Databáze: | OpenAIRE |
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