Thermal reaction of pentachlorophenol and its salts

Autor:	Ing-Luen Shiau, Gary D. McGinnis
Rok vydání:	1991
Předmět:	Potassium Inorganic chemistry chemistry.chemical_element Analytical Chemistry Pentachlorophenol Thermogravimetry chemistry.chemical_compound Fuel Technology Reaction rate constant chemistry Yield (chemistry) Phenol Lithium Pyrolysis
Zdroj:	Journal of Analytical and Applied Pyrolysis. 18:341-352
ISSN:	0165-2370
DOI:	10.1016/0165-2370(91)87011-a
Popis:	Studies were done on the thermal reaction of pentachlorophenol and its sodium, lithium and potassium salts. Thermal reactions were characterized using isothermal and dynamic thermogravimetry and a variety of chemical analysis techniques. Large differences were observed between pentachlorophenol and different pentachlorophenate salts. Oxygen and various levels of bases had little effect on the thermal reaction. The yield of octachlorodibenzo- p -dioxin varies depending on the type of inorganic ion and the temperature. The other major product was a polymer formed by condensation of the initial starting material (phenol), an intermediate, or the final product (dioxin). Preliminary evidence indicated it was very similar to the structure of octachlorodibenzo- p -dioxin.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::e6384581ef9c8e3e759c49411570a794 https://doi.org/10.1016/0165-2370(91)87011-a Zobrazit plný text záznamu