On the reaction mechanism of MoS42− with nitric oxide

Autor:	Eric Maimon, Naomi Meyerstein, Israel Zilbermann, Dror Shamir, Inna Popivker, Dan Meyerstein
Rok vydání:	2010
Předmět:	chemistry.chemical_classification Reaction mechanism Aqueous solution Inorganic chemistry Rate equation Photochemistry Nitric oxide Inorganic Chemistry chemistry.chemical_compound Hydrolysis chemistry Nitrosation Materials Chemistry Thiol Physical and Theoretical Chemistry Nitrite
Zdroj:	Inorganic Chemistry Communications. 13:589-592
ISSN:	1387-7003
DOI:	10.1016/j.inoche.2010.02.010
Popis:	MoS 4 2− (TTM) reacts in deaerated neutral phosphate buffered aqueous solutions with NO. Three consecutive reactions are observed. The two first ones obey pseudo first order rate laws with observed rates proportional to [NO]. The third reaction obeys a first order rate law. Nitrite is one of the final products. The mechanism proposed involves thiol nitrosation via a radical mechanism followed by hydrolysis of the S–N bond. The findings indicate that if MoS 4 2− will be used as a drug, it will not affect considerably the NO concentration in the system.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::e6109548e4238913b8865fb8e4bbcb46 https://doi.org/10.1016/j.inoche.2010.02.010 Zobrazit plný text záznamu Full Text from ScienceDirect