The influence of electron-withdrawing substituents on the adsorption of CO on copper
| Autor: | B. R. Zegarski, L.H. Dubois |
|---|---|
| Rok vydání: | 1985 |
| Předmět: |
chemistry.chemical_classification
Base (chemistry) Formic acid Inorganic chemistry General Physics and Astronomy chemistry.chemical_element Copper Chloride chemistry.chemical_compound Adsorption chemistry Chemisorption medicine Lewis acids and bases Physical and Theoretical Chemistry Carbon monoxide medicine.drug |
| Zdroj: | Chemical Physics Letters. 120:537-541 |
| ISSN: | 0009-2614 |
| DOI: | 10.1016/0009-2614(85)80550-9 |
| Popis: | The chemisorption of carbon monoxide on Cu(100) in the presence of either methyl chloride or formic acid results in an increase in the the CO stretching frequency to above the gas-phase value and a simultaneous increase in the heat of adsorption of CO. We explain this behavior qualitatively in terms of the simple Lewis acid/base character of both the surface and the adsorbate. |
| Databáze: | OpenAIRE |
| Externí odkaz: |
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