CO2 hydrogenation to lower hydrocarbons over ZSM-5-supported catalysts in a dielectric-barrier discharge plasma reactor
| Autor: | Anjie Wang, Yao Wang, Liying Lan |
|---|---|
| Rok vydání: | 2019 |
| Předmět: |
chemistry.chemical_classification
Materials science 010405 organic chemistry Process Chemistry and Technology Inorganic chemistry General Chemistry Plasma Dielectric barrier discharge 010402 general chemistry Plasma reactor 01 natural sciences Catalysis 0104 chemical sciences Metal Hydrocarbon chemistry visual_art visual_art.visual_art_medium ZSM-5 Selectivity |
| Zdroj: | Catalysis Communications. 130:105761 |
| ISSN: | 1566-7367 |
| DOI: | 10.1016/j.catcom.2019.105761 |
| Popis: | ZSM-5-supported metal catalysts, including Fe/ZSM-5, Co/ZSM-5, Ni/ZSM-5, Cu/ZSM-5 and Mo/ZSM-5, were tested for the plasma-induced CO2 hydrogenation in a dielectric-barrier discharge (DBD) plasma reactor. A significant synergy between DBD plasma and the catalyst was found. Without catalyst, CO2 was converted solely to CO at a conversion level of 8.1% in the plasma. The supported metal catalysts enhanced CO2 conversion and promoted the hydrocarbon formation. Co/ZSM-5 exhibited the best performance with a C2-C4 selectivity of 13.7% at 45.0% CO2 conversion. Powder XRD studies revealed that the stable active phase was Co metal particles in the Co/ZSM-5 catalyst. |
| Databáze: | OpenAIRE |
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