Analyte-triggered luminescence of Eu3+ ions encapsulated in Nafion membranes -preparation of hybrid materials from in membrane chemical reactions
| Autor: | María de Jesús Gálvez-Vázquez, Iván Zelocualtecatl-Montiel, Rutilo Silva-González, R. Aguilar-Sánchez |
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| Rok vydání: | 2017 |
| Předmět: |
Materials science
Inorganic chemistry Infrared spectroscopy chemistry.chemical_element 02 engineering and technology 010402 general chemistry 021001 nanoscience & nanotechnology Condensed Matter Physics 01 natural sciences Chemical reaction Oxalate Fluorescence spectroscopy 0104 chemical sciences chemistry.chemical_compound Membrane chemistry General Materials Science 0210 nano-technology Hybrid material Europium Luminescence |
| Zdroj: | Materials Chemistry and Physics. 191:206-214 |
| ISSN: | 0254-0584 |
| DOI: | 10.1016/j.matchemphys.2017.01.051 |
| Popis: | The possibility to perform chemical reactions inside polymer materials opens a unique opportunity to control and prepare materials for diverse solid-state applications. Based on the affinity of Eu3+ ions for oxygen functionalities, in this work we report the luminescence enhancement of Eu3+ ions inserted in Nafion membranes (Naf/Eu3+) by in-situ complexing to oxalate. The formation of a europium-oxalate type complex enhances Eu3+ luminescence emission, which could be exploited for the construction of devices for oxalate sensing and the fabrication of highly luminescent materials. Possible analytical applications of Naf/Eu3+ membranes were evaluated by fluorescence spectroscopy through the linear response with concentration. The complex formation was followed by infrared spectroscopy and SEM-EDS analysis. |
| Databáze: | OpenAIRE |
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