Development of Various Metal Sulfide Photocatalysts Consisting of d0, d5, and d10 Metal Ions for Sacrificial H2 Evolution under Visible Light Irradiation
| Autor: | Tsutomu Okuda, Tomoaki Takayama, Hideki Kato, Harada Masamitsu, Akihiko Kudo, Akihide Iwase, Issei Tsuji, Naruhiko Aono |
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| Rok vydání: | 2017 |
| Předmět: |
chemistry.chemical_classification
Sulfide Metal ions in aqueous solution Inorganic chemistry chemistry.chemical_element 02 engineering and technology General Chemistry Electron Zinc Crystal structure 010402 general chemistry 021001 nanoscience & nanotechnology Photochemistry 01 natural sciences 0104 chemical sciences Metal chemistry visual_art visual_art.visual_art_medium Electron configuration 0210 nano-technology Solid solution |
| Zdroj: | Chemistry Letters. 46:616-619 |
| ISSN: | 1348-0715 0366-7022 |
| DOI: | 10.1246/cl.161192 |
| Popis: | We have developed metal sulfide photocatalysts with various crystal structures and constituent metal cations with d0, d5, and d10 electron configurations. Cu3VS4, Cu3NbS4, and Cu3TaS4 with a sulvanite structure, ZnGaxIn2−xS4 (x = 0–0.6), and MnGaInS4 with layered structures, BaLaCuS3 with a one-dimensionally anisotropic structure along the b-axis, and a (ZnS)0.9-(CuCl)0.1 solid solution with a zinc blende structure have arisen as new photocatalysts for H2 evolution in the presence of sacrificial electron donors under visible light irradiation. |
| Databáze: | OpenAIRE |
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