Supramolecular polymer materials based on pillar[5]arene: Ultrasensitive detection and efficient removal of cyanide
| Autor: | Hong Yao, Tai-Bao Wei, Guan-Fei Gong, Yan-Yan Chen, Qin-Peng Zhang, Xiao-Tong Kan, You-Ming Zhang, Qi Zhou, Hu Yinping, Qi Lin |
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| Rok vydání: | 2020 |
| Předmět: |
Detection limit
chemistry.chemical_classification Aqueous solution Cyanide Inorganic chemistry Pillar 02 engineering and technology General Chemistry 010402 general chemistry 021001 nanoscience & nanotechnology 01 natural sciences 0104 chemical sciences Supramolecular polymers chemistry.chemical_compound chemistry 0210 nano-technology |
| Zdroj: | Chinese Chemical Letters. 31:1231-1234 |
| ISSN: | 1001-8417 |
| DOI: | 10.1016/j.cclet.2019.09.046 |
| Popis: | An ultrasensitive detection and effective removal material was successfully developed by using a pillar[n]arene-based supramolecular polymer gel (MTP5⊃HB). The MTP5⊃HB can ultrasensitively recognize Cu2+ and Fe3+, and the limits of detection (LODs) for Cu2+ and Fe3+ are 1.55 and 2.68 nmol/L, respectively. Additionally, the in-situ generated metallogel MTP5⊃HB-Cu can exclusively detect CN−, and the LOD for CN− is 1.13 nmol/L. Noticeably, the xerogel of MTP5⊃HB-Cu can effectively remove CN− from aqueous solution with 94.40% removal rate. Test kit based on MTP5⊃HB-Cu is also prepared for convenient detection of CN−. |
| Databáze: | OpenAIRE |
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