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The direct formation of hydrogen peroxide from H 2 and O 2 was successfully carried out in a capillary microreactor at room temperature and atmospheric pressure. A key element in sustaining the activity of the catalyst is the incarceration of the palladium nanoparticles in a cross-linkable amphiphilic polystyrene-based polymer, prepared following the protocol of Kobayashi [R. Akiyama, S. Kobayashi, J. Am. Chem. Soc. 125 (2003) 3412–3413]. The immobilization effectively reduced the leaching of palladium under acidic conditions. Applying the catalyst as a coating on the inner walls of a capillary enabled the sustained production of 1.1% hydrogen peroxide over at least 11 days. The highest catalyst utilization in a 2 mm capillary reactor was 0.54 mol H2O2 /h g Pd . When the inner diameter of the reactor capillary was reduced to 530 μm, the rate was enhanced fourfold to 2.28 mol H2O2 /h g Pd corresponding to a turnover frequency of 0.067 s −1 . |
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