Deduction of structures of lanthanoid coordination compounds from absorption spectra

Autor:	K. B. Yatsimirskii, N. K. Davidenko, N. A. Kostromina, T. V. Ternovaya
Rok vydání:	1965
Předmět:	chemistry.chemical_classification Lanthanide Absorption spectroscopy Inorganic chemistry Ionic bonding General Chemistry Electron Coordination complex Ion Metal chemistry visual_art Linear relation visual_art.visual_art_medium Physical chemistry Condensed Matter::Strongly Correlated Electrons
Zdroj:	Theoretical and Experimental Chemistry. 1:65-68
ISSN:	1573-935X 0040-5760
DOI:	10.1007/bf00526486
Popis:	The nepheloxetic effect (reduction in the electron repulsion parameter B in a coordination compound relative to that in the gaseous ion) indicates that the bond type deviates from ionic. There is a linear relation between the long-wave shift δv (difference in wave-numbers for the bands in the compound and aqua-ion) and B for the d-transition metals; δv is dependent on the type of bond from the metal to the addend.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::e5e557f12afa3d67f91db9e359488773 https://doi.org/10.1007/bf00526486 Zobrazit plný text záznamu Full text from SpringerLink