ChemInform Abstract: Dicobalt Octacarbonyl Promoted Rearrangement of 4-Isoxazolines to Acylaziridines: Dramatic Rate Acceleration with Very High Substrate Tolerance

Autor:	Shinobu Manabe, Ayako Yasuhara, Juri Yoshida, Takayuki Kudoh, Teruhiko Ishikawa, Seiki Saito
Rok vydání:	2010
Předmět:	chemistry.chemical_compound Valence (chemistry) chemistry Substrate (chemistry) chemistry.chemical_element General Medicine Acetonitrile Photochemistry Dicobalt octacarbonyl Cleavage (embryo) Medicinal chemistry Cobalt
Zdroj:	ChemInform. 33
ISSN:	1522-2667 0931-7597
DOI:	10.1002/chin.200242116
Popis:	Dicobalt octacarbonyl [Co2(CO)8] in acetonitrile at 75 °C triggers the cleavage of the N−O bond of 4-isoxazolines (1) to bring about the valence rearrangement to 2-acylaziridines (2). The isoxazolines were stable at 75 °C in the absence of the cobalt complex.
Databáze:	OpenAIRE
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