Vibrational spectra of the isoelectronic species IF5, TeF5–, and SbF52–

Autor: Lesley E. Alexander, I. R. Beattie
Rok vydání: 1971
Předmět:
Zdroj: J. Chem. Soc. A. :3091-3095
ISSN: 0022-4944
DOI: 10.1039/j19710003091
Popis: Gas-phase Raman spectra on iodine pentafluoride, and single-crystal Raman studies on KTeF5 and K2SbF5 are reported. The liquid-phase spectrum of iodine pentafluoride is discussed in terms of an associated fluid. Assignments for these molecules suggest that the (e type) antisymmetric stretching vibration is unusually low relative to the position of the highest-frequency Raman band.
Databáze: OpenAIRE