Thieno[3,4-c]pyrrole-4,6-dione-based conjugated polymers for organic solar cells
| Autor: | Nanfu Yan, Dongdong Xia, Weiwei Li, Zhao Chaowei, Zhou Zhang, Shengyong You, Zhang Yuefeng, Fan Yang |
|---|---|
| Rok vydání: | 2020 |
| Předmět: |
chemistry.chemical_classification
Fullerene Materials science Organic solar cell Band gap Metals and Alloys Nanotechnology General Chemistry Polymer Conjugated system Acceptor Catalysis Surfaces Coatings and Films Electronic Optical and Magnetic Materials chemistry.chemical_compound chemistry Polymerization Materials Chemistry Ceramics and Composites Pyrrole |
| Zdroj: | Chemical Communications. 56:10394-10408 |
| ISSN: | 1364-548X 1359-7345 |
| DOI: | 10.1039/d0cc04150e |
| Popis: | Conjugated polymers consisting of electron-rich and electron-deficient units as alternative structures have played important roles in the field of organic solar cells (OSCs). A thieno[3,4-c]pyrrole-4,6-dione (TPD) unit as an electron-deficient unit has been used to construct conjugated polymers for application in fullerene and non-fullerene based OSCs. TPD-based monomers can be simply prepared and TPD-polymers can be synthesized via environmentally friendly direct (hetero)arylation polymerization, providing a possibility for large quantity preparation. TPD-polymers usually have deep frontier energy levels, wide band gaps with absorption onset around 700 nm and good charge transport properties, showing the advantages of high open-circuit voltage, high fill-factor and excellent spectral matching with a small band gap non-fullerene acceptor. From the material design and synthesis and their optoelectrical properties, TPD-polymers have great potential applications in OSCs toward large-area devices. In this review, we provide an overview of TPD-polymers for OSCs in the last ten years, including the design and synthesis of TPD-polymers, and their application in fullerene and non-fullerene OSCs. We will also provide some perspective about the research of TPD-polymers that meet the requirement of OSCs. We hope that our universal summary can stimulate the study of TPD-polymers in the future, especially toward high performance, low cost and stable OSCs. |
| Databáze: | OpenAIRE |
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