Hydrolysis of Epoxidized Soybean Oil in the Presence of Phosphoric Acid

Autor:	Yinzhong Guo, John L. Massingill, Jon H. Hardesty, Vijay Mannari
Rok vydání:	2007
Předmět:	food.ingredient General Chemical Engineering Organic Chemistry Dispersity Soybean oil Solvent Epoxidized soybean oil chemistry.chemical_compound Hydrolysis food Vegetable oil chemistry Molar mass distribution Organic chemistry Phosphoric acid
Zdroj:	Journal of the American Oil Chemists' Society. 84:929-935
ISSN:	1558-9331 0003-021X
DOI:	10.1007/s11746-007-1126-5
Popis:	Ring-opening hydrolysis of epoxidized soybean oil in the presence of phosphoric acid was studied under varying experimental conditions. The influence of type and amount of solvents, phosphoric acid content and water content on the rate of ring-opening reactions and the characteristics of the derived products were studied. The soy-polyols prepared were characterized by determination of hydroxyl content, viscosity measurements, determination of average molecular weight and polydispersity index (GPC). The structural confirmation was done by FT-IR and 1H-NMR spectroscopy. The study shows that under the reaction conditions employed, a substantial degree of oligomerization due to oxirane-oxirane, and/or oxirane-hydroxyl reaction takes place. It is possible to synthesize soy-polyols having varying hydroxyl content and phosphate-ester functionality by controlling the type and amount of polar solvent and phosphoric acid content.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::e58bfb39583e249ac43cf84cc27d9337 https://doi.org/10.1007/s11746-007-1126-5 Zobrazit plný text záznamu Full text from SpringerLink Plný text