Two Novel Sm and La Metal-Organic Frameworks Suggesting the Reductive Coupling of Carbon Dioxide (CO2) to Oxalate (C2O42-): {[Ln(HPIDC)•(μ4-C2O4)0.5·H2O]·2H2O}n.(Ln=Sm or La)

Autor:	Xing-Xing Cao, Li-Zhuang Chen, Yuan-Yuan Dan
Rok vydání:	2015
Předmět:	Samarium chemistry.chemical_compound Chemistry Carbon dioxide Lanthanum Physical chemistry Mineralogy chemistry.chemical_element Metal-organic framework General Chemistry Hydrothermal circulation Oxalate
Zdroj:	Journal of Chemical Research. 39:14-19
ISSN:	2047-6507 1747-5198
DOI:	10.3184/174751915x14183173493268
Popis:	Complexes formulated as {[Ln(HPIDC)(μ4-C2O4)0.5(H2O)]·2H2O}n [Ln=Sm or La; H3PIDC=2-(pyridin-4-yl)-1H-imidazole-4,5-dicarboxylic acid] have been synthesised under hydrothermal conditions. The complexes are both built up from T-shaped 3-connected HPIDC2- and 4-connected metal nodes and contain bridging oxalate (C2O42-) ligands, which might have been formed by the reductive coupling of CO2 molecules released from the HPIDC2- ligands through C-C bond cleavage.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::e5845a0f73c61517b1c801088df19b06 https://doi.org/10.3184/174751915x14183173493268 Zobrazit plný text záznamu Plný text ve formátu PDF