Synthesis and characterization of bis(trialkoxysilymethyl)arenes from related bis(trichlorosilylmethyl)arenes. Comparisons between some organosilicate xerogel materials derived from both

Autor:	Stuart W. Carr, Majid Motevalli, Alice C. Sullivan, Duan Li Ou
Rok vydání:	1997
Předmět:	Stereochemistry Aryl Infrared spectroscopy Sorption General Chemistry Crystal structure Medicinal chemistry chemistry.chemical_compound chemistry Solid-state nuclear magnetic resonance Materials Chemistry Disilane Spectroscopy Sol-gel
Zdroj:	Journal of Materials Chemistry. 7:865-872
ISSN:	1364-5501 0959-9428
DOI:	10.1039/a607633e
Popis:	A series of bis(trialkoxysilylmethyl)aryl compounds1–17 {[(RO) 3 SiCH 2 ] 2 Ar, R=Me, Et, Pr , Bu, Ar=1,4-C 6 H 4 ; R=Et, Pr, Bu, Ar=1,4-C 6 H 2 Me 2 -2,6; R=Et, Pr, Bu, Ar=1,4-C 6 Me 4 -2,3,5,6 ; R=Et, Pr, Bu, Ar=1,3-C 6 H 4 ; R=Bu, Ar=1,2-C 6 H 4 ; R=Et, Pr, Bu, Ar=9,10-C 14 H 8 } prepared from the related bis(trichlorosilylmethyl)aryl compounds and characterised by 1 H, 13 C and 29 Si NMR and IR spectroscopy, and high resolution mass spectrometry. The X-ray crystal structures of two of the bis(trichlorosilylmethyl)aryl precursor compounds are reported. Organosilicate xerogels prepared from the precursors 2,7 and 12 are discussed. These have been studied by a combination of solid state NMR spectroscopy, scanning electron microscopy (one case) and nitrogen sorption porosimetry and their properties compared with those of xerogels derived from related bis(trichlorosilylmethyl)arenes.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::e52f40f0ed8d21c7d573cbd62d283059 https://doi.org/10.1039/a607633e Zobrazit plný text záznamu