Reduction of CO2 by hydrated electrons in high temperature water
| Autor: | David M. Bartels, Alexandra Lisovskaya |
|---|---|
| Rok vydání: | 2019 |
| Předmět: |
Arrhenius equation
Radiation Materials science 010308 nuclear & particles physics Analytical chemistry Electron Activation energy Atmospheric temperature range 01 natural sciences 030218 nuclear medicine & medical imaging Reaction rate 03 medical and health sciences symbols.namesake 0302 clinical medicine 0103 physical sciences Radiolysis Ultrafast laser spectroscopy symbols Spectroscopy |
| Zdroj: | Radiation Physics and Chemistry. 158:61-63 |
| ISSN: | 0969-806X |
| DOI: | 10.1016/j.radphyschem.2019.01.017 |
| Popis: | The reaction rate of hydrated electrons, (e-)aq, with CO2 was measured in water using transient absorption spectroscopy and electron pulse radiolysis over the temperature range from 5 to 350°C. Arrhenius activation energy is found to be 15.9 kJ/mol between 5 °C and 200 °C. The reaction of (e-)aq with CO2 in high-temperature water showed non-Arrhenius behavior similar to that of its reaction with isoelectronic N2O, reaching a maximum at 300 °C. |
| Databáze: | OpenAIRE |
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