New Titanocene Complexes [Cp2Ti(μ-S2)2NR] (with R = Me and n Oct) as Transfer Reagents for the Synthesis of the Heterocycles S5NR and S6NR

Autor: Oliver Schumann, Ralf Steudel
Rok vydání: 1997
Předmět:
Zdroj: Phosphorus, Sulfur, and Silicon and the Related Elements. 124:529-532
ISSN: 1563-5325
1042-6507
DOI: 10.1080/10426509708545676
Popis: The reaction of 1,4-S4(NR)2 with (η5-C5H5)2Ti(CO)2 yields [Cp2Ti(μ-S2)2NR] which on treatment with SCl2 or S2Cl2 provides the novel heterocycles S5NR and S6NR (R = Me, Oct).
Databáze: OpenAIRE