Water-Stable In(III)-Based Metal–Organic Frameworks with Rod-Shaped Secondary Building Units: Single-Crystal to Single-Crystal Transformation and Selective Sorption of C2H2 over CO2 and CH4
| Autor: | Lin-Hua Xie, Jiamei Yu, Yufeng Wu, Jian Zhang, Jian-Rong Li, Guo Zhenji, Yong-Zheng Zhang, Ya Chen |
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| Rok vydání: | 2017 |
| Předmět: |
Acrylate
Stereochemistry Chemistry Ligand 02 engineering and technology 010402 general chemistry 021001 nanoscience & nanotechnology 01 natural sciences 0104 chemical sciences Inorganic Chemistry chemistry.chemical_compound Crystallography Molecule Metal-organic framework Carboxylate SBus Physical and Theoretical Chemistry 0210 nano-technology Single crystal Dichloromethane |
| Zdroj: | Inorganic Chemistry. 56:2188-2197 |
| ISSN: | 1520-510X 0020-1669 |
| Popis: | Three new water-stable In(III)-based metal–organic frameworks, namely, [In3(TTTA)2(OH)3(H2O)]·(DMA)3 (BUT-70, DMA = N,N-dimethylacetamide), [In3(TTTA)2(CH3O)3] (BUT-70A), and [In3(TTTA)2(OH)3] (BUT-70B), with rod-shaped secondary building units (SBUs) and an new acrylate-based ligand, (2E,2′E,2″E)-3,3′,3″-(2,4,6-trimethylbenzene-1,3,5-triyl)-triacrylate (TTTA3–) were obtained and structurally characterized. BUT-70A and -70B were generated in a single-crystal to single-crystal transformation fashion from BUT-70 through guest exchange followed by their removal. The solvents used for guest exchange were methanol and dichloromethane, respectively. Single-crystal structure analyses show that the guest exchange and removal process is accompanied by the substitution of coordinated water molecules of In(III) centers with uncoordinated carboxylate O atoms of TTTA3– ligands. Moreover, hydroxyl groups bridging two In(III) centers are also replaced by methoxyl groups in the transformation from BUT-70 to -70A. Overall... |
| Databáze: | OpenAIRE |
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