CAl11−: a molecular rotor with a quasi-planar tetracoordinate carbon

Autor:	Li-Xia Bai, Jorge Barroso, Mesías Orozco-Ic, Filiberto Ortiz-Chi, Jin-Chang Guo, Gabriel Merino
Rok vydání:	2023
Předmět:	Materials Chemistry Metals and Alloys Ceramics and Composites General Chemistry Catalysis Surfaces Coatings and Films Electronic Optical and Magnetic Materials
Zdroj:	Chemical Communications. 59:4966-4969
ISSN:	1364-548X 1359-7345
DOI:	10.1039/d3cc00855j
Popis:	The global minimum of CAl11− is formed by two stacked layers, one of them resembles the well-known planar tetracoordinate carbon CAl4 on top of a hexagonal Al@Al6 wheel. The CAl4 fragment rotates freely around the central axis with a negligible barrier.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::e47eab854e2aeaac8d189aceda3b0d37 https://doi.org/10.1039/d3cc00855j Zobrazit plný text záznamu