Electrochemical oxidation of 1-phenylpyrazolidin-3-one in acetonitrile

Autor:	Trevor A. Joslin, Brian D. Baigrie, Harry H. Adam
Rok vydání:	1977
Předmět:	chemistry.chemical_compound chemistry Inorganic chemistry Protonation Oxidative phosphorylation Cyclic voltammetry Electrochemistry Acetonitrile
Zdroj:	Journal of the Chemical Society, Perkin Transactions 2. :1287
ISSN:	1364-5471 0300-9580
Popis:	The electrochemical oxidation of 1-phenylpyrazolidin-3-one in acetonitrile has been studied. Two oxidation waves were observed using cyclic voltammetry and these were found to be due to the oxidation of the protonated and neutral compound. Controlled potential electrolyses resulted in the isolation of two main components which were 1-phenylpyrazolin-3-one (75%) and 3-anilino-N-[4-(3-oxopyrazolin-l-yl)phenyl]propionamide (20%). The oxidative mechanism which results in these two products is discussed.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::e46b9aff0f64930fd95cb6bcabcff643 https://doi.org/10.1039/p29770001287 Zobrazit plný text záznamu