Structure and Thermodynamic Properties of the DyGaTi2O7 and EuGaTi2O7 Titanates
Autor: | Liubov G. Chumilina, N. V. Belousova, Liubov T. Denisova, V. V. Ryabov, Maxim S. Molokeev, Yu. F. Kargin, Viktor M. Denisov |
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Rok vydání: | 2021 |
Předmět: | |
Zdroj: | Inorganic Materials. 57:733-740 |
ISSN: | 1608-3172 0020-1685 |
DOI: | 10.1134/s0020168521070050 |
Popis: | The DyGaTi2O7 and EuGaTi2O7 titanates have been prepared by solid-state reactions in a starting mixture of Dy2O3 (Eu2O3), Ga2O3, and TiO2 via firing in air at temperatures of 1273 and 1573 K, and their crystal structure has been studied by X-ray diffraction. Their high-temperature heat capacity (350–1000 K) has been determined by differential scanning calorimetry. The Cp(T) experimental data have been used to calculate the thermodynamic functions of the titanates. |
Databáze: | OpenAIRE |
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