Synthetic manifestation of nitro substituted tetrazole-N-(hetero)aryl derivatives and energetic studies
| Autor: | M. Balaraju, Nagarjuna Kommu, Akhila K. Sahoo, Vikas D. Ghule |
|---|---|
| Rok vydání: | 2017 |
| Předmět: |
Exothermic reaction
Renewable Energy Sustainability and the Environment Chemistry Aryl 02 engineering and technology General Chemistry 010402 general chemistry 021001 nanoscience & nanotechnology 01 natural sciences Decomposition Energetic material Combinatorial chemistry 0104 chemical sciences chemistry.chemical_compound Nitro Organic chemistry General Materials Science Tetrazole 0210 nano-technology |
| Zdroj: | Journal of Materials Chemistry A. 5:7366-7371 |
| ISSN: | 2050-7496 2050-7488 |
| DOI: | 10.1039/c6ta10621h |
| Popis: | A workable cost-efficient synthetic method for the construction of nitro substituted tetrazole-N-aryl/heteroaryl derivatives is discussed here. The energetic functional groups –NO2, –NHNO2 and –N3 are reliably inserted into the molecular backbone, making the tetrazole-N-aryl derivatives highly energetic and insensitive to heat and impact. For example, the tetrazole derivatives 7 and 8, bearing a –NO2 or a –NHNO2 group, exhibit energetic properties close to RDX, but with enhanced insensitivity. Most of the synthesized compounds show exothermic decomposition and are consequently useful for energetic material applications. |
| Databáze: | OpenAIRE |
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