Macrocyclic and open-chain ligands with the redox switchable trithiadiazapentalene unit: synthesis, structures and complexation phenomena

Autor:	Wilhelm Seichter, Heinz Graubaum, Melinda Wüst, Karsten Gloe, Torsten Rambusch
Rok vydání:	2001
Předmět:	Chemistry Crystal structure Block (periodic table) Ring (chemistry) Redox Crown Compounds Inorganic Chemistry Bond length Metal Phase (matter) visual_art Polymer chemistry Materials Chemistry visual_art.visual_art_medium Physical and Theoretical Chemistry
Zdroj:	Coordination Chemistry Reviews. 222:103-126
ISSN:	0010-8545
Popis:	This review focuses on synthesis, structure and binding properties of crown compounds and their open-chain analogues containing a trithiadiazapentalene building block. This heterocyclic unit favours in particular the complexation and solvent extraction of the soft transition metal ions Ag(I), Pd(II), Hg(II) and Au(III). The redox active system trithiadiazapentalene/trithiotriuret introduced into a crown ring allows the control of Ag(I) and Hg(II) phase transfer in solvent extraction experiments. Crystal structures of metal complexes with these pentaleno crown compounds show significant differences of both SS bond lengths of the trithiadiazapentalene unit and package arrangements in the cell.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::e421e62a6126c15542cc64d0e9de1717 https://doi.org/10.1016/s0010-8545(01)00397-6 Zobrazit plný text záznamu Full Text from ScienceDirect