Synthesis of amidoglucals and glucal esters via carbonylative coupling reactions of 2-iodoglucal using Mo(CO)6 as a CO source
| Autor: | Mariana P. Darbem, Karina S. Kanno, Hélio A. Stefani, Daniel C. Pimenta, Isadora M. de Oliveira, C. Henrique A. Esteves |
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| Rok vydání: | 2019 |
| Předmět: |
Substrate (chemistry)
02 engineering and technology General Chemistry 010402 general chemistry 021001 nanoscience & nanotechnology 01 natural sciences Catalysis Coupling reaction 0104 chemical sciences chemistry.chemical_compound chemistry Polymer chemistry Materials Chemistry 0210 nano-technology Glucal Carbon monoxide |
| Zdroj: | New Journal of Chemistry. 43:696-699 |
| ISSN: | 1369-9261 1144-0546 |
| Popis: | The synthesis of amidoglucals and glucal esters in good to high yields using 2-iodo-3,4,6-tri-O-acetyl-D-glucal as a substrate, Mo(CO)6 as a carbon monoxide source and PdCl2 as a catalyst is reported. This procedure shows advantages when compared to other published methodologies, as it is carried out in one pot relying on short reaction times at mild temperatures, under ligand-free conditions and with only one equivalent of Mo(CO)6. |
| Databáze: | OpenAIRE |
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