The photochemistry of palladium and platinum homo- and heteronuclear metal-metal .sigma.-bonds: efficient photogeneration of 15-electron radicals

Autor:	Mark K. Reinking, Marc L. Kullberg, Clifford P. Kubiak, Ann R. Cutler
Rok vydání:	1985
Předmět:	Reaction mechanism Isocyanide Radical chemistry.chemical_element Quantum yield General Chemistry Photochemistry Biochemistry Catalysis chemistry.chemical_compound Colloid and Surface Chemistry chemistry Heteronuclear molecule Acetonitrile Platinum Palladium
Zdroj:	Journal of the American Chemical Society. 107:3517-3524
ISSN:	1520-5126 0002-7863
Popis:	Photochimie de MM'(CNMe) 2+ 6 avec M=M'=Pd; M=Pd, M'=Pt. Obtention des radicaux M(CNMe) + 3 . Reaction de ceux-ci avec CCl 4 ou CBr 4 conduisant a MCl(CNMe) + 3 ou MBr(CNMe) + 3 . Rendements quantiques, mecanisme, cinetique
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::e41b13ccf6e6cfa96a27ea6acda58d66 https://doi.org/10.1021/ja00298a019 Zobrazit plný text záznamu