Article
| Autor: | Steven M Barnett, Antonín Vlcek, Jr., Ian S Butler |
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| Rok vydání: | 1998 |
| Předmět: | |
| Zdroj: | Canadian Journal of Chemistry. 76:158-163 |
| ISSN: | 1480-3291 0008-4042 |
| DOI: | 10.1139/v97-222 |
| Popis: | Pressure-tuning infrared and Raman spectroscopic studies were performed on (2,2'-bipyridine)tetracarbonyl-chromium(0), Cr(CO)4(bpy). Previous bpy ring mode assignments were confirmed with new assignments offered by examination of the pressure-induced alterations in the vibrational spectra. The electron-density distribution of the bipyridyl ligand (and consequently, the electron-donating ability to the central metal) is modulated by the application of pressure. The pressure dependence of the carbonyl moieties reveals that the bipyridyl ligand can accommodate a significant portion of the molecular compressibility at higher pressures.Key words: infrared, Raman, pressure, Cr(CO)4(bpy), metal carbonyl. |
| Databáze: | OpenAIRE |
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