A novel quasi-one-dimensional zig-zag platinum atom chain in K1.75Pt(CN)4.1.5H2O. A neutron diffraction study

Autor:	Jack M. Williams, Donald M. Washecheck, Nancy P. Enright, Keith D. Keefer
Rok vydání:	1976
Předmět:	Hydrogen bond Neutron diffraction chemistry.chemical_element General Chemistry Crystal structure Biochemistry Catalysis Bond length Crystallography Colloid and Surface Chemistry Molecular geometry Chemical bond chemistry Molecule Platinum
Zdroj:	Journal of the American Chemical Society. 98:233-234
ISSN:	1520-5126 0002-7863
DOI:	10.1021/ja00417a038
Popis:	The potassium deficient cyanoplatinate complex, K/sub 1.75/Pt(CN)/sub 4/.1.5H/sub 2/O was prepared and the results of a single-crystal neutron diffraction study are reported. The basic repeat unit of the zig-zag metal atom chain was found to include three crystallographically independent Pt atoms. Bond angles and lengths are reported; a discussion of water molecule hydrogen bonding to cyanide ligands is included. (DDA)
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::e3e64ad6df373b992c2e8ebf7c80542d https://doi.org/10.1021/ja00417a038 Zobrazit plný text záznamu