Nitrones and Oxaziridines. XXV. Bromination of 2-t-Butyl- and 2-Phenyl-1-pyrroline 1-Oxides

Autor:	Dsc Black, NA Blackman
Rok vydání:	1979
Předmět:	Green chemistry Reaction mechanism Bromine chemistry.chemical_element Halogenation General Chemistry Pyrroline Medicinal chemistry Copper chemistry.chemical_compound chemistry Bromide Biocatalysis Organic chemistry
Zdroj:	Australian Journal of Chemistry. 32:1795
ISSN:	0004-9425
DOI:	10.1071/ch9791795
Popis:	Certain 2-t-butyl- and 2-phenyl-1-pyrroline 1-oxides undergo bromination but no 3-bromo compounds could be observed, although their intermediacy is proposed. The isolated products are 2H-pyrrole 1-oxide derivatives-further brominated in some cases. 4-Bromo-3-oxo-1-pyrroline 1-oxides and 4,4-dibromo-3-oxo-1-pyrroline 1-oxides can be formed by treatment of the related oxo nitrones with copper(II) bromide and bromine respectively.
Databáze:	OpenAIRE
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