Palladium-catalyzed decarboxylative [2 + 3] cyclocarbonylation reactions of [60]fullerene: selective synthesis of [60]fullerene-fused 3-vinylcyclopentan-4-ones and cyclopentane-4-carbaldehydes

Autor: Tong-Xin Liu, Chuanjie Zhang, Pengling Zhang, Xin Wang, Jinliang Ma, Guisheng Zhang
Rok vydání: 2022
Předmět:
Zdroj: Organic Chemistry Frontiers. 9:5564-5570
ISSN: 2052-4129
DOI: 10.1039/d2qo01116f
Popis: A new palladium-catalyzed decarboxylative strategy has been developed toward direct cyclocarbonylation of [60]fullerene, selectively furnishing novel [60]fullerene-fused 3-vinylcyclopentan-4-ones and cyclopentane-4-carbaldehydes.
Databáze: OpenAIRE