Synthesis of Semifluorinated Block Copolymers Containing Poly(ε-caprolactone) by the Combination of ATRP and Enzymatic ROP in scCO2

Autor:	Christopher J. Duxbury, Steven M. Howdle, Silvia Villarroya, Jiaxiang Zhou, and Andreas Heise
Rok vydání:	2005
Předmět:	Polymers and Plastics Atom-transfer radical-polymerization Organic Chemistry Solution polymerization Ring-opening polymerization Inorganic Chemistry chemistry.chemical_compound chemistry Polymerization Polycaprolactone Polymer chemistry Materials Chemistry Copolymer Bifunctional Caprolactone
Zdroj:	Macromolecules. 39:633-640
ISSN:	1520-5835 0024-9297
DOI:	10.1021/ma052142p
Popis:	The synthesis of novel diblock copolymers consisting of a semifluorinated block of poly(1H,1H,2H,2H-perfluorooctyl methacrylate) (PFOMA) and a hydrocarbon block of polycaprolactone (PFOMA-b-PCL) was achieved by the combination of enzymatic ring-opening polymerization (eROP) and atom transfer radical polymerization (ATRP). The chemoenzymatic synthesis of diblock copolymers from a bifunctional initiator in two consecutive steps was investigated. A polycaprolactone (PCL) macroinitiator was obtained via enzymatic ring-opening polymerization initiated by the bifunctional initiator. A PFOMA block was then grown from this PCL macroinitiator. In addition, block copolymers were successfully prepared by a two-step−one-pot synthesis using a sequential monomer addition technique.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::e3b0b8f39f312b98ebeb391f783eb05b https://doi.org/10.1021/ma052142p Zobrazit plný text záznamu