Electrophoretic deposition of a self-stabilizing suspension based on a nanosized multi-component electrolyte powder prepared by the laser evaporation method
| Autor: | I.V. Nikolaenko, E.G. Kalinina, A.V. Menshikova, E. Yu. Pikalova |
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| Rok vydání: | 2016 |
| Předmět: |
Thermogravimetric analysis
Materials science Non-blocking I/O Analytical chemistry Sintering Nanoparticle 02 engineering and technology General Chemistry 010402 general chemistry 021001 nanoscience & nanotechnology Condensed Matter Physics 01 natural sciences Evaporation (deposition) 0104 chemical sciences Electrophoretic deposition visual_art Differential thermal analysis visual_art.visual_art_medium General Materials Science Ceramic 0210 nano-technology |
| Zdroj: | Solid State Ionics. 288:110-114 |
| ISSN: | 0167-2738 |
| Popis: | This work presents the results of study of non-aqueous suspensions based on a solid state electrolyte Се 0.8 (Sm 0.75 Sr 0.2 Ba 0.05 ) 0.2 O 2-δ (CSSBO) prepared by the method of high-energy material dispersion–laser evaporation of the ceramic target. The thermal behavior of the powder was studied by thermogravimetric and differential thermal analysis (TG-DTA); the sintering kinetic was investigated by the dilatometric method. Electrokinetic study showed that the powders with nanoparticles that had an average diameter of 15 nm formed a self-stabilizing suspension with a high value of ζ-potential (+ 31 mV) in the isopropanol/acetylacetone (50/50 vol.%) dispersing medium. The CSSBO thin films (2 μm) that deposited on the dense electrode substrate of La 2 NiO 4 + δ (LNO) after sintering for 6 h at 1400 °C had a uniform microstructure with an average grain size of 4 μm and total conductivity of 0.1 S/cm at 650 °C. |
| Databáze: | OpenAIRE |
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