Fungal macrolides: Structure determination and biosynthesis of achaetolide, a lactone from Achaetomium cristalliferum

Autor:	Bernard Bodo, Darius Molho, Lucie Molho, Daniel Davoust
Rok vydání:	1983
Předmět:	chemistry.chemical_classification biology Stereochemistry Plant Science General Medicine Horticulture Achaetomium Carbon-13 NMR biology.organism_classification Biochemistry NMR spectra database chemistry.chemical_compound chemistry Biosynthesis Molecular Biology Lactone
Zdroj:	Phytochemistry. 22:447-451
ISSN:	0031-9422
DOI:	10.1016/0031-9422(83)83021-0
Popis:	The structure of a new ten-membered lactone, achaetolide, isolated from cultures of Achaetomium cristalliferum is deduced from its mass and NMR spectra and from the study ofsomederivatives. The 13 C NMR spectra of achaetolide enriched with [1- 13 C], [2- 13 C] and [1, 2- 13 C] acetate established its formation from eight intact acetate units via a precursor octaketide chain.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::e3a1c52154f582d5e24918827b863593 https://doi.org/10.1016/0031-9422(83)83021-0 Zobrazit plný text záznamu