Kinetics and mechanism of the reaction of a quasi-aromatic nickel(II) complex, [Ni((PnAO)-6H]0, with formaldehyde

Autor:	Yun Ti Chen, Qi Yan Zhang, R. Kent Murmann, Bin Song
Rok vydání:	1992
Předmět:	Cyclic compound Reaction mechanism Formaldehyde chemistry.chemical_element Reaction intermediate Metallacycle Inorganic Chemistry Metal chemistry.chemical_compound Nickel Reaction rate constant chemistry visual_art Polymer chemistry visual_art.visual_art_medium Physical and Theoretical Chemistry
Zdroj:	Inorganic Chemistry. 31:2314-2317
ISSN:	1520-510X 0020-1669
Popis:	The reaction of [Ni((PnAO)-6H)] 0 (2,2,3,9,10,10-hexamethyl-5,7-dioxa-6-hydra-1,4,8,11-tetraazacyclotetradeca-3,8, 11,13-tetraenc)nickel(11) (abbreviated to AH), a quasi-aromatic metal ion complex, with formaldehyde has been studied spectrophotometrically. The Ni, 2N, 3C quasi-aromatic heterocyclic ring in AH is highly reactive at the central-aromatic-carbon atom, C12, to most aldehydes.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::e3982b926476818dfadb2066d8a027d1 https://doi.org/10.1021/ic00038a006 Zobrazit plný text záznamu