The study of induced aquation of Rh(III) sulfate complexes

Autor: S. N. Shagabutdinova, M. A. Fedotov, A. V. Belyaev
Rok vydání: 2007
Předmět:
Zdroj: Russian Journal of Coordination Chemistry. 33:140-144
ISSN: 1608-3318
1070-3284
DOI: 10.1134/s1070328407020121
Popis: The processes of aquation of Rh(III) complexes in the presence of BaCl2 and Ba(ClO4)2 were studied by the 103RH and 17O NMR methods. In the first case, the final products were found to be the monomeric aqua chloride complexes, while in the second case, aqua hydroxo complexes were formed. The chloride ions present in the system significantly increase the process rate.
Databáze: OpenAIRE